基本信息

姓名：艾勇

性别：男

职称：教授

学位：博士

专业：化学

电子邮箱：yong.ai@ncu.edu.cn

研究方向：分子铁电材料

教育工作经历

2006.09-2010.07 兰州大学化学化工学院 化学专业，获学士学位

2010.09-2013.07 兰州大学化学化工学院 有机化学专业，获硕士学位

2013.10-2016.10 法国巴黎第七大学（现巴黎西岱大学）ITODYS 物理化学专业, 获博士学位

2017.02-2018.08 荷兰格罗宁根大学博士后，合作导师Ryan C. Chiechi教授

2018.09-至今 南昌大学国际有序物质科学研究院工作

教学简介

本科生《有机化学》课程、研究生《分子铁电基础》课程

科研简介

致力于分子铁电的化学设计与性能优化，精准构筑了具有高相变温度、多极轴特性的系列高性能分子铁电材料，拓展了分子基多铁材料新体系。近五年以第一作者或通讯作者身份在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Adv. Mater.等化学类国际权威期刊上发表论文30余篇。

科研项目

国家自然科学基金青年基金项目1项（24.5万）、主持、结题

国家自然科学基金面上项目1项（54万），主持、在研

江西省主要学科和学术带头人青年项目1项（50万），主持、在研

承担国家自然科学基金重大项目子课题100万经费，参与、在研

获奖情况

指导学生参加2024中国国际大学生创新大赛获国家级铜奖

指导学生参加第七届江西省“互联网+”大学生创新创业大赛，获得省级金奖

指导学生参加第十八届“ 挑战杯” 南昌大学大学生课外学术科技作品竞赛，获得特等奖

入选第二十六批江西省主要学科学术和技术带头人

南昌大学第十六批教学成果特等奖，排名第四

成果入选2023年度江西省十大创新成果（排名第一）

代表性论文

1. Ai, Y.; Hu, Z.-B.; Weng, Y.-R.; Peng, H.; Qi, J.-C.; Chen, X.-G.; Lv, H.-P.; Song, X.-J.; Ye, H.-Y.; Xiong, R.-G.; Liao, W.-Q. A Multiferroic Spin-Crossover Molecular Crystal. Adv. Mater. 2024, 36 , 202407822.

2. Ai, Y.; Gu, Z.-X.; Wang, P.; Tang, Y.-Y.; Chen, X.-G.; Lv, H.-P.; Li, P.-F.; Jiang, Q.; Xiong, R.-G.; Zhang, J.-J.; Zhang, H.-Y. Biodegradable Ferroelectric Molecular Plastic Crystal HOCH2(CF2)7CH2OH Structurally Inspired by Polyvinylidene Fluoride. Adv. Mater. 2024, 36, 202405981.

3. Ai, Y.; Liao W.-Q.;* Weng Y.-R.; Lv H.-P.; Chen X.-G.; Song X.-J.; Li P.-F.; and Xiong R.-G.* Discovery of Ferroelectricity in the Fullerene Adduct C60S8. J. Am. Chem. Soc. 2023, 145, 23292.

4. Ai, Y.; Chen, X.-G.; Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Xiong, R.-G.* Fluorine Substitution Induced High Tc of Enantiomeric Perovskite Ferroelectrics: (R)- and (S)-3-(Fluoropyrrolidinium)MnCl3. J. Am. Chem. Soc. 2019, 141, 4474.

5. Ai, Y.; Zeng, Y.-L.; He, W.-H.; Huang, X.-Q.; Tang, Y.-Y.* Six-Fold Vertices in a Single-Component Organic Ferroelectric with Most Equivalent Polarization Directions. J. Am. Chem. Soc. 2020, 142, 13989.

6. Zeng, Y.-L.; Ai, Y. ,; Tang, S.-Y.; Song, X.-J.; Chen, X.-G.; Tang, Y.-Y.; Zhang, Z.-X.; You, Y.-M.; Xiong, R.-G;* and Zhang H.-Y.* Axial-Chiral BINOL Multiferroic Crystals with Coexistence of Ferroelectricity and Ferroelasticity. J. Am. Chem. Soc. 2022, 42, 19559-19566.

7. Ai, Y.;* Sun, R.; W.-Q. Liao; Song X.-J.; Tang, Y.-Y.; Wang, B.-W.; Wang, Z.-M.; Gao, S.;* Xiong, R.-G.* Unprecedented Ferroelectricity and Ferromagnetism in a Cr2+-based Two-Dimensional Hybrid Perovskite. Angew. Chem. In. Ed. 2022, 134, e202206034.

8. Fu, D.-W.;* Gao, J.-X.; He, W.-H.; Huang, X.-Q.; Liu, Y.-H.; Ai, Y.* High-T(c)Enantiomeric Ferroelectrics Based on Homochiral Dabco-derivatives (Dabco=1,4-Diazabicyclo 2.2.2 octane). Angew. Chem. In. Ed. 2020, 59, 17477.

9. Liu, J.-C.; Ai, Y.; Liu, Q.; Zeng, Y.-P.; Chen, X.-G.; Lv, H.-P.; Xiong, R.-G.; Liao, W.-Q. Solid-Liquid Crystal Biphasic Ferroelectrics with Tunable Biferroelectricity. Adv. Mater. 2023, 35, 2302436.

10. Ai, Y.; Li, P.-F.; Chen, X.-G.; Lv H.-P.; Weng, Y.-R.; Shi, Y.; Zhou, F.; Xiong R.-G.;* and Liao W.-Q.;* The First Ring Enlargement Induced Large Piezoelectric Response in a Polycrystalline Molecular Ferroelectric. Adv. Sci. 2023, 10, 2302426.

11. Ai, Y.; Lv H.-P.; Wang, Z.-X.;* Liao, W.-Q.; Xiong, R.-G.* H/F substitution for advanced molecular ferroelectrics. Trends Chem. 2021, 3, 1088.

12. Ai, Y.; Sun, R.; Zeng, Y.-L.; Liu, J.-C.; Tang, Y.-Y.; Wang, B.-W.; Wang, Z.-M.; Gao, S.;* Xiong, R.-G.* Coexistence of magnetic and electric orderings in a divalent Cr2+-based multiaxial molecular ferroelectric. Chem. Sci. 2021, 12, 9742.

13. Ai, Y.; Li, P.-F.; Yang, M.-J.; Xu, Y.-Q.; Li, M.-Z.; Xiong, R.-G., An organic plastic ferroelectric with high Curie point. Chem. Sci. 2022, 13, 748.

14. Li, P.-F.; Ai, Y.;(共一)；Zeng, Y.-L.; Liu J.-C.; Xu Z.-K.; Wang Z.-X. Highest-Tc single-component homochiral organic ferroelectrics. Chem. Sci., 2022, 13, 657.

15. Song X.-J.; Tang S.-Y.; Chen X.-G. Ai, Y.* Chemical Design Homochiral Heterocyclic Organic Ferroelectric Crystals. Chem. Commun. 2022, 58, 10361.

16. Ai, Y.;* Wu, D.-J.; Yang, M.-J.; Wang, P.; He, W.-H.; Liao, W.-Q.,* Highest-T(c)organic enantiomeric ferroelectrics obtained by F/H substitution. Chem. Commun. 2020, 56, 7033.

17. Yang, M.-J.; Tang S.-Y.; Weng Y.-R.; Zhou F., Shi Y.; Bai Y.-J. and Ai Y.* H/F Substitution on the Spacer Cations Leads to 1D-to-2D Increment of the Pyrrolidinium-Containing Lead Iodide Hybrid Perovskites. Inorg. Chem. 2022, 61, 5836.

18. Weng, Y.-R.; Zhou, F.; Shi, Y.; Tang, S.-Y.; Lv, H.-P.;* Yang, M.-J.; Tang, Y.-Y.; Ai, Y.* H/F Substitution Achieved Enantiomeric Organic Inorganic Hybrid Perovskites and Trigonal Structure [DMFP]3(CdBr3)(CdBr4). Inorg. Chem. 2023, 62, 19930.

19. Zhou F.;  Weng, Y.-R.; Shi, Y.; Yu, Y.-H.; Lu, D.; Yu, Y.; She, J.-Z.; Ai, Y.;* Plastic phase transitions in tris(hydroxymethyl) aminomethane perchlorate. Dalton Trans. 2024, 53, 7965.

20. Shi, Y.; Weng, Y.-R.; Zhou F.; Ai, Y.;* Crystalline water induced nonpolar‐to‐polar transition and high piezoelectric response in lamivudine hydrate crystal. Chem. Select, 2024, 9, e202304533.

21. Yang, M.-J.; Xu, Y.-Q.; Li, M.-Z.; Ai, Y.* A hybrid organic-inorganic perovskite with robust SHG switching. Chin. Chem. Lett. 2022, 33, 2143.

22. Peng, H.; Cheng, H.; Liu, Y.-H.; Yang, M.-J.; Liao, W.-Q.; Ai, Y.* Enantiomeric perovskite with a dual phase transition at high temperature. J. Mater. Chem. C 2021, 9, 1918.

23. Cheng, H.; Yang, M.-J.; Xu, Y.-Q.; Li, M.-Z.; Ai, Y.* Target Designing Phase Transition Materials through Halogen Substitution. Chem. Phys. Chem. 2021, 22, 752.

24. Liu, Y.-Y.; Liu, Z.-Q.; Wang, Y.-Q.; Zhou, Y.; Qin, Y.; Lv, H.-P.; Li, P.-F.;* Chen, X.-G.; Song, * X.-J.;* Ai, Y.* Light-Driven Domain Switching on a Photochromic Ferroelectric. Cryst. Growth Des. 2023, 23, 2602.

25. Zhang Y. F.; Tang S. Y.; Xu Y. Q.; Li M. Z.; Cheng S. P.; Ai Y. * Halogen substitution assisted modification on phase transition point and band gap of (DBU) PbX3 (X = Cl, Br, I). J. Solid State Chem. 2022, 312, 123198.

26. Ai, Y.;* Lacroix, J.-C.,* Self-terminated fabrication of electrochemically-gated conducting polymer nanojunctions. Electrochem. Commun. 2020, 112, 106674.

27. Qiao, L.; Chen, X.-G.; Gao, J.-X.; Ai, Y.;* Three new quinuclidine-based structures: second harmonic generation response for 1,2-bis­(1-azoniabi­cyclo­[2.2.2]octan-3-yl­idene)hydrazine dichloride. Acta Cryst. C 2019, C75, 728.

28. Ai, Y.; Kovalchuk, A.; Qiu, X.; Zhang, Y.; Kumar, S.; Wang, X.; Kühnel, M.; Nørgaard, K.; Chiechi, R. C.,* In-Place Modulation of Rectification in Tunneling Junctions Comprising Self-Assembled Monolayers. Nano Lett. 2018, 18, 7552.

29. Lacroix, J. C.*, Nguyen, V. Q., Ai, Y., Nguyen, V. N., Pascal M., Lacaze, P. C. From active plasmonic devices to plasmonic molecular electronics. Polymer International 2019, 68, 607.

30. Ai, Y.; Nguyen, V. Q., Ghilane, J., Lacaze, P. C;* Lacroix, J.-C.* Plasmon-Induced Conductance Switching of an Electroactive Conjugated Polymer Nanojunction. ACS Appl. Mater. Interfaces, 2017, 9, 27817.

31. Ai, Y.; Smida, H.; Ghilane, J.;* Vilà, N.; Ghanbaja, J.; Walcarius, A.; Lacroix, J. C.* Copper Nanowires through Oriented Mesoporous Silica: A Step towards Protected and Parallel Atomic Switches. Sci. Rep. 2017, 7, 17752.

32. Ai, Y.; Ghilane, J.;* Lacroix, J. C.* Approaching the Frontier Between Fiber Devices and Single Molecule Devices in Redox Gated Junction. J. Phys. Chem. C 2015 119, 21278.